Choose the previous instrument for the next step, but the indicated parameters below to draw the upper lip on the girl’s face:

Gradient Overlay:

Gradient’s parameters:

The same instrument will help to create a highlight of white color on the lower lip:

Use the same instrument to dark out the girl’s face, but turn to account the parameters below:

Gradient Overlay:

Gradient’s parameters:

Fill 0% in the layer. Make use of the same instrument to draw the girl’s eyes of black color:

Continue drawing the girl’s eyes. Create the white of the eyes:

Use the already known instrument to create the eyelids with the color 681525:

Use the same instrument to draw the eye pupils of black color:

The same instrument will help us to hide a part of the right eye under the hat. The white color:

The instrument will help to create circle with the parameters demonstrated in the picture:

Stroke:

Fill 0% in the layers
Use the instrument to dark out the girl’s hat, making use of the following parameters:

Gradient Overlay:

Gradient’s parameters:

Fill 0% in the layers.
The last feature consists of adding the eyebrow of black color by the eye:

The final result!