Create a new layer and apply the Soft Round brush of white color (set Opacity to 30% in Options bar).

Use this brush to paint as on the next screen:

Hold down Alt (Windows) or Option (Mac OS) and click between the brush’s layers and the model’s one in the Layers panel to create a clipping mask.

Set Fill to 82% for this layer.

Create a new layer and apply on it the Paint Bucket Tool (G) to fill it of the color #2B3B77.

Hold down Alt (Windows) or Option (Mac OS) and click between layers in the Layers panel to create a clipping mask.

Set Fill to 96% for this layer and change the Blending mode to Vivid Light.

Click Create new fill or adjustment layer from bottom part of the Layers panel and click to Curves to adjust the curve shape as shown to make a little color corrections.

We’ve got the next result:

Create a new layer and apply on it the Paint Bucket Tool (G) to fill it of this color #000014.

Set the Blending mode for this layer to Exclusion.

Create a new layer and apply the Soft Round brush to paint several zones on the model, using this color for the brush #1F3C78.

We’ve got the next result:

Set the Blending mode for this layer to Lighten.

Create a new layer again and apply the Soft Round brush of white color (brush Opacity – 70%) to represent a highlight on the model:

We’ve got the next result: